When Ubuntu 9.10 releases, pppoe connection via NetworkManager is impossible because some bug in it so to fix this we will install network manager from daily network manager trunk ppa.
(...)Re...
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16752 Responseshttp://linuxing.info/how-to-setup-networkmanager-work-with-pppoe-connection-on-ubuntu-9-10-karmic/How+to+setup+NetworkManager+work+with+pppoe+connection+on+Ubuntu+9.10+%28Karmic%292009-11-27+15%3A07%3A46PaulpBaker to “How to setup NetworkManager work with pppoe connection on Ubuntu 9.10 (Karmic)”
simply change the value of the "/etc/NetworkManager/nm-system-settings.conf"
…
[ifdown]
managed=true
…
than restart the Network-Manager with su privileges /etc/init.d/network-manager restart
its working on 9.10 amd64 ubuntu
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